The History of Crack

Anecdotally at least, the history of Crack is a bit like this:
Cocaine was trafficked from South America by a group of Yaqui Native Americans who started to cut the cocaine with cheaper substances. In order to gauge how strong the drug really was, the purchasers started washing the cocaine in ether and water (the cocaine alkaloid would dissolve in the ether) siphoning the ether and allowing it to evaporate to leave almost pure powder cocaine. By measuring the difference in weight between the original powder and what was left, the purity of the drug could be estimated. This also turned the acidic cocaine hydrochloride salt into a smokeable alkaline base. There are several disadvantages to Freebase Cocaine: it isn't stable and quickly looses its potency; and it involves volatile chemicals such as ether which are highly flammable.

In the mid-1970's producers moved away from the use of ammonia and ether towards the less dangerous use of bicarbonate of soda, which when mixed with cocaine powder and heated results in a relatively pure, anhydrous cocaine base. This base is quite stable and can easily be mass produced and sold as crack rather than the end using having to do it.